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Potassium (K), element 19

Potassium (K) is the chemical element with atomic number 19: an alkali metal in group 1, period 4. At 25 °C it is a solid, with an atomic mass of 39.1 u. Its electronegativity of 0.82 is among the lowest measured: it gives electrons away with extreme ease.

Physical and chemical data

Atomic number19
SymbolK
Atomic mass39.1 u
Density0.89 g/cm³
Melting point63.38 °C (336.53 K)
Boiling point758.85 °C (1,032 K)
Electronegativity (Pauling)0.82
Electron configuration[Ar]4s1
Atomic radius (van der Waals)275 pm
Oxidation states+1
Physical state at 25 °Csolid
Familyalkali metal
Group and period1 / 4
Discoverer and yearHumphry Davy (1807)

The discovery record belongs to Humphry Davy, in 1807.

Neighbours on the table

Horizontally, one proton less lands on Argon (Z=18); one more lands on Calcium (Z=20). Vertically, group 1 gathers relatives with similar behaviour: Hydrogen, Lithium, Sodium, Rubidium.

The story behind the name

The name comes from potash, plant ash leached in pots and used as fertiliser and soap; the symbol K comes from the Latin kalium, inherited from the Arabic al-qalyah, plant ashes, the same root as the word alkali. It was the first metal ever isolated by electrolysis: in 1807 Humphry Davy drove the current of his giant battery through molten potash and watched metallic globules burst into lilac flames; by his brother's account, Davy danced around the laboratory in delight. Its natural radioactive isotope, potassium-40, makes every banana a tiny and harmless radiation source.

Physical and chemical data: PubChem Periodic Table (NCBI, compiling NIST and IUPAC), public domain, snapshot of 2026-07-10. Temperatures converted from kelvin; historical notes cross checked against classic chemistry references.

Last updated: · Methodology and sources